Ok, this is how your captcha image looks like inside:
Now, this how it should look like:
See these extra 3 bytes at the beginning? these are BOM indicator for text in UTF8 encoding. This means a file on your server is saved in UTF8 encoding with BOM and until you find that file and replace it with ASCII encoded your captcha won't work and nobody can help you.
Now that you know the cause, the problem is almost solved...just find the file
P.S. just trace your steps, what files have you edited?
P.P.S. I don't see much of modifications on your site, maybe you should update your 4images?